Sunlight activated film forming adhesive polymers
نویسندگان
چکیده
Stimuli-sensitive biomaterials that are activated by light in need of formulations stable under indoor lighting yet can be direct sunlight. Carbene-based bioadhesives a new generation film-forming polymers rapidly with low-energy UVA light, but have never been evaluated sunlight exposure. Previous investigations evolved two flexible carbene-based platforms, where aryl-diazirine is grafted on to polyamidoamine dendrimers (PAMAM-NH2; generation-5) or hydrophobic liquid polycaprolactone tetrol yield G5-Dzx and CaproGlu, respectively. For the first time activation CaproGlu investigated natural intensities up 10 mW·cm−2. Structure-property relationships bioadhesion by: (1) joules dose sunlight; (2) bioadhesive polymer structure; (3) optical concentrators magnifying glass Fresnel lens. Using only sunlight, adhesion strength could tuned from 20 150 kPa crosslinking achieved 1 min. The results show class stimuli-sensitive lighting, which may useful for topical film forming as active ingredients sunscreen formulations.
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ژورنال
عنوان ژورنال: Materials Science and Engineering: C
سال: 2021
ISSN: ['1873-0191', '0928-4931']
DOI: https://doi.org/10.1016/j.msec.2021.112240